金活动态提取剂提取-电感耦合等离子体质谱法测定深穿透地球化学样品中的金     

王冀艳  胡家祯  丁汉铎  曹立峰  张明炜  张帆  黄杰  姚文生 《岩矿测试》2020,39(4):525-534

金的地球化学勘查基于金的准确测定,地球化学样品中金含量通常处于ng/g水平,需先进行分离富集,再采用电感耦合等离子体质谱法(ICP-MS)或石墨炉原子吸收光谱法(GFAAS)进行测定。当前,隐伏矿床勘查是地球化学探测技术的发展前沿,金活动态提取技术是寻找隐伏金矿的有效手段之一。相比于全量分析,金的活动态含量更低,需要解决选择性提取、高效预富集与准确测定等一系列难题。本文采用柠檬酸铵与土壤中黏土矿物及次生矿物作用促使吸附和可交换组分的金进入提取液,以硫脲和硫代硫酸钠络合金使活动态金向提取液中扩散,达到选择性提取的目的,建立了提取液中金的预富集及ICP-MS测定方法。实验确定的分析条件为:采用5g/L柠檬酸铵-2g/L硫脲-5g/L硫代硫酸钠为提取剂,提取时间24h,在酸性硫脲介质下用活性炭富集金,金吸附率可达89.6%～109.2%,灰化解吸温度为650～700℃。本方法检出限为0.05ng/g,相对标准偏差(RSD)为9.4%～10.2%,加标回收率为91.2%～93.4%。与已报道的硫酸铁-硫脲-硫代硫酸钠溶液提取再GFAAS测定的方法相比,本方法具有检出限低、测试线性范围宽、测试速度快的优势;应用于森林覆盖区黑龙江东安金矿区地球化学探测试验,金活动态异常与隐伏金矿位置一致。  相似文献   

云南哀牢山-红河剪切带新生代富碱侵入岩中榍石年代学和地球化学特征     

马倩  杨岳衡  赵志丹  佟鑫  武精凯  苗壮  李晨  雷杭山 《岩石学报》2020,36(9):2751-2764

榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱(Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS)与激光剥蚀系统(Laser Ablation,LA)联用,对哀牢山-红河剪切带5个富碱侵入岩体(桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体)中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce*比值,具有较低的Eu/Eu*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5～37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期(～35Ma)一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MCICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8～-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。  相似文献   

压裂微震数据初至拾取的时频谱熵法     

田雅男  王环宇  王鑫  黄佳俊  章强 《吉林大学学报(地球科学版)》2020,50(4):1219-1227

在油气田开发过程中，微震监测是获得水力压裂引起裂缝分布的一种较为有效的方法。微震的定位成像与裂缝解释需要利用有效微震信号位置，而微震信号具有低信噪比的特点，传统信号拾取方法无法有效实现较低信噪比条件下初至时刻的准确拾取。本文提出一种基于时频谱熵的初至拾取新方法，该方法首先通过S变换获取含噪信号的时频谱；然后对谱内各个采样点沿频率方向进行分帧操作，并计算每帧频段内的近似负熵值，以最小近似负熵值作为该谱点的负熵值；最后沿时间方向比较各谱点的负熵值，最小值对应的时刻即为初至时刻。本文利用不同信噪比的合成地震数据对该方法进行效果验证，并与长短时窗能量比（STA/LTA）法进行拾取结果对比，结果表明：信噪比在-5 dB时，两种方法拾取效果都很好；信噪比在-10 dB时，时频谱熵法拾取效果更好。时频谱熵法更适合低信噪比情况下的信号初至拾取。  相似文献   

南极中山站全天信息采集系统     

王宇  辛玉新  姜鹏  杨勇  伦宝利  王传军  余晓光  常亮  范玉峰 《天文研究与技术》2021,(2):272-282

南极高原拥有独特的天文观测优势,为了对南极中山站夜天文观测条件进行实测研究,中国科学院云南天文台专门研制了一套具有耐低温、自动除雪除霜等适应南极气候特征的全自动全天信息采集系统,该系统可以提供实时的全天云量、天光背景和全天图像,并将信息推送到网页实时显示。介绍了系统的研制及为适应南极气候进行的耐低温实验,统计分析了中山站2016~2017年的全天信息数据,结果显示,中山站2016和2017年的可观测时间为772.21 h和437.38 h,可观测夜数为93 d和51 d,天光背景最大真实值为22.05 Mag/arcsec 2,年平均气温为-10.6℃,最高气温19.1℃,最低气温为-44℃,2016年平均相对湿度为55.2%。  相似文献   

利用双视角消除太阳矢量磁场观测中的180◦不确定性          下载免费PDF全文

周茹芸  汪毓明  宿英娜  毕少兰  刘睿  季海生 《天文学报》2021,62(4):41

随着"环日轨道器"(Solar Orbiter, SO)的在轨运行,太阳磁场观测进入了双视角遥测的时代.对利用太阳磁场的双视角观测改正矢量磁图中存在的横场(垂直于视线方向的磁场分量) 180°不确定性进行了模拟,首先模拟了对解析解得到磁图的双视角观测,然后利用"日震学和磁学成像仪"(Helioseismic and Magnetic Imager, HMI)在不同时间观测到的一个老化黑子的磁图模拟了双视角观测.发现要改正一个磁图中横场方向的180°不确定性,在观测上只需要另外一个平行于视线方向的磁场即纵向磁场观测的协助.利用HMI的磁场观测模拟,估算显示30°的张角能够改正50 Gs磁场中的180°不确定性.更大的张角虽然更有利于更弱磁场的改正,但是考虑到投影效应的不利影响, 30°左右的张角应该是未来空间设备进行多视角观测太阳磁场的最佳张角.  相似文献   

Hydrological management strategies for the control of algal blooms in regulated lowland rivers     

Jian Li  Wei Yin  Haiyan Jia  Xiaokang Xin 《水文研究》2021,35(6):e14171

Reservoirs of lowland floodplain rivers with eutrophic backgrounds cause variations in the hydrological and hydraulic conditions of estuaries and low-dam reservoir areas, which can promote planktonic algae to proliferate and algal bloom outbreaks. Understanding the ecological effects of variations in hydrological and hydraulic processes in lowland rivers is important for algal bloom control. In this study, the middle and lower reaches of the Han River, China, a typical regulated lowland river with a eutrophic background, are selected. Based on the effect of hydrological and hydraulic variability on algal blooms, a hydrological management strategy for river algal bloom control is proposed. The results showed that (a) differences in river morphology and background nutrient levels cause significant differences in the critical threshold flow velocities for algal bloom outbreaks between natural river and low-dam reservoir sections; there is no uniform threshold flow velocity for algal bloom control. (b) There are significant differences in the river hydrological/hydraulic conditions between years with and without algal blooms. The average river flow, water level and velocity in years with algal blooms are significantly lower than those in years without algal blooms. (c) For different river sections where algal blooms occur and to meet the threshold flow velocities, the joint operation of cascade reservoirs and diversion projects is an effective method to prevent and control algal blooms in regulated lowland rivers. This study is expected to deepen our understanding of the ecological significance of special hydrological processes and guide algal bloom management in regulated lowland rivers.  相似文献   

广盐性鱼类渗透压适应性与生理可塑性机制研究     

马爱军  崔文晓  刘志峰  张金生  黄智慧  杨双双  刘晓菲  杨凯  张薇 《海洋与湖沼》2018,49(6):1308-1317

拥有强大的渗透压调节能力对广盐性鱼类的生存至关重要。目前,关于鱼类渗透压调节机制已有不少研究,但均存在较大的局限性。本文从广盐性鱼类渗透压信号转导机制、渗透胁迫的细胞调控机制、渗透调控的内分泌调节机制和无机离子通道和转运蛋白介导的渗透调控等方面对广盐性鱼类的渗透压适应性和生理可塑性机制进行分析,以期从分子、细胞、通路和生理等层次初步探索广盐性鱼类盐度胁迫后的可塑性表型变化和不同盐度条件下的应答机制,为广盐性鱼类的渗透压调节机制的深入研究奠定基础。对广盐性鱼类渗透压适应性与生理可塑性机制研究,有助于研究其环境适应机理,促进野生鱼种的人工化养殖以及新品种的育种从而提高经济效益、社会效益和生态效益,对促进水产养殖学进步以及养殖业的发展具有重要意义,同时,为研究广盐性鱼类的渗透压调节机制开辟新的研究方向。  相似文献   

Changes of Biogenic Elements in Phragmites australis and Suaeda salsa from Salt Marshes in Yellow River Delta,China     

JIA Jia  BAI Junhong  WANG Wei  ZHANG Guangliang  WANG Xin  ZHAO Qingqing  ZHANG Shuai 《中国地理科学(英文版)》2018,(3)

Little information is available on biogenic elements(carbon, nitrogen, phosphorus and sulfur) and the ecological stoichiometric characteristics of plants in coastal wetlands. To investigate the contents of carbon, nitrogen, phosphorus and sulfur of plants, and their ecological stoichiometric characteristics in the Yellow(Huanghe) River Delta, plant samples were collected from two typical salt marshes(Suaeda salsa and Phragmites australis wetlands) during the period of from August to October in 2007, and the ratios of C/N, C/P, N/P, C/N/P and C/N/P/S were calculated. Results showed that during the studying period, plant C, N and P were lower than the global average values, and plant N and P were lower than the China's average values. Leaf C and S in Suaeda salsa were significantly lower than those in Phragmites australis(P 0.05), and leaf N and P in Suaeda salsa and Phragmites australis showed no significant differences(P 0.05). Average C/N ratios were 23.75 in leaf, 73.36 in stem, 65.67 in root of Suaeda salsa, and 33.77 in leaf, 121.68 in stem, 97.13 in root of Phragmites australis. Average C/N ratios of Suaeda salsa and Phragmites australis were all great than 25, indicating the salt marsh in the Yellow River Delta is an N limitation system. Average C/P ratios were 276.78 in leaf, 709.28 in stem and 1031.32 in root of Suaeda salsa, and 536.94 in leaf, 768.13 in stem and 875.22 in root of Phragmites australis. The average N/P ratios of Suaeda salsa were 12.92 in leaf, 10.77 in stem and 10.91 in root, and the average N/P ratios of Phragmites australis were 16.40 in leaf, 7.40 in stem and 6.92 in root, indicating the Suaeda salsa wetlands were N limited and Phragmites australis wetlands were N limited in August and P limited in October in 2007. The average C/N, C/P and C/N/P ratios in Suaeda salsa and Pragmites australis were higher than the global average values, indicating the lower quality of organic matter provided by wetland plants in the Yellow River delta.  相似文献   

The Influence of Two Kinds of El Niño Events on the Strong Tropical Cyclone Generation and Strength in the Pacific Ocean     

Xingchi Wang  Shuzong Han  Xin Wang  Yujie Dong 《中国海洋大学学报(英文版)》2018,17(5):1011-1018

This paper focuses on the effects of two types of El Niño events on tropical cyclone activity. We classified El Niño events from 1961 to 2015 according to their sea surface temperature (SST) anomalies into an eastern type and a central type. Then we selected strong tropical cyclones to statistically analyze the tropical cyclone characteristics during different events and their effects, as well as to study the possible mechanisms related to thermodynamic and dynamic factors. The tropical cyclone generation areas were found to be very similar during the two kinds of events. The average number of tropical cyclone in the eastern event is more than that in central event, and the hurricane in northeastern Pacific (HNP) has more energy than the typhoon in northwestern Pacific (TNP) in all cases. The seasonal distribution of the TNP high-incidence centers during central El Niño events is opposite to that of the HNP. The TNP accumulated cyclone energy (ACE) intensity is similar in the fall and summer, and the HNP ACE intensity in the summer is greater than that in the fall. The SSTs are consistent with the TNP and HNP movement trends. The Walker circulation intensity was strongly affected by the eastern events, but it quickly returned to its normal state, while the intensity was slightly reduced in the central events, and it slowly returned to its normal state. The vertical velocity distributions in the Pacific are different at different stages of both events, and the distributions of vertical velocity anomalies for typhoons and hurricanes are consistent.  相似文献   

基于VSD模型的铁山港湾红树林生态系统脆弱性初步评价   总被引：2，自引：0，他引：2  

李小维  黄子眉  陈剑锋  王欣  韦江玲 《热带海洋学报》2018,37(2):47-54

基于脆弱性域图 (vulnerability scoping diagram, VSD)评价模型, 从暴露程度、敏感性、适应能力3个方面构建了红树林生态系统脆弱性评价指标体系。采用改进的综合指数法和模糊综合评价法, 重新定义脆弱性分级标准, 定量评价了铁山港湾红树林生态系统在1989年、2003年和2014年3个年份的脆弱性水平。结果显示, 铁山港湾红树林生态系统在3个年份的脆弱性水平值分别为0.145、0.255、0.334, 呈现增加趋势。首先, 铁山港湾红树林生态系统面临的暴露程度不断增大, 主要胁迫因子为滩涂围垦面积、废水排放量; 其次, 生态系统的敏感性增强, 主要敏感因子是海洋生物质量综合指数、底栖生物和潮间带生物多样性指数; 第三, 生态系统的适应能力略有增加, 总体上较弱。  相似文献